منابع مشابه
Zirconium and hafnium complexes containing bidentate diarylamido-phosphine ligands.
The first examples of mononuclear, structurally characterized triarylphosphine complexes of zirconium and hafnium are reported. The metathetical reactions of MCl4(THF)2 (M = Zr, Hf) with [iPrNP]Li(THF)2 ([iPrNP]- = N-(2-(diphenylphosphino)phenyl)-2,6-diisopropylanilide) or [MeNP]Li(THF)2 ([MeNP]- = N-(2-(diphenylphosphino)phenyl)-2,6-dimethylanilide) in toluene at -35 degrees C produced the cor...
متن کاملSeparation of hafnium from zirconium using tributyl phosphate
The separation of hafnium from zirconium using tributyl phosphate offers interesting alternatives to present methods for making reactor-grade zirconium. Feed solution for the extraction step can be prepared from the reaction product of caustic and zircon sand. The purified zirconium can be converted into a variety of compounds, depending on the process chosen for reduction to the metal. It may ...
متن کاملAtomic Layer Deposition of Insulating Hafnium and Zirconium Nitrides
Highly uniform, smooth, and conformal coatings of higher nitrides of hafnium and zirconium were produced by atomic layer deposition from homoleptic tetrakis(dialkylamido)metal(IV) complexes and ammonia at low substrate temperatures (150-250 °C). The precursor vapors were alternately pulsed into a heated reactor, yielding 1.15-1.20 Å of metal nitride film for every cycle. Successful depositions ...
متن کاملZirconium and hafnium Salalen complexes in isospecific polymerisation of propylene.
The activity of dibenzylzirconium and dibenzylhafnium Salalen complexes in polymerisation of propylene with MAO as a cocatalyst is described. Three Salalen ligand precursors combining a bulky alkyl group (1-adamantyl) on the imine-side phenol and electron withdrawing halo groups of different sizes on the amine-side phenol were explored. All metal complexes were obtained as single diastereomers....
متن کاملSolvent extraction and separation of hafnium from zirconium using Ionquest
industries, its nuclear properties in the pure metallic form make it highly desirable for nuclear applications. Zr is highly corrosion resistant and has a high melting point (2128 K) with a low thermal neutron absorption cross-section of Zr T = 0.18 b, which is significantly smaller than that of hafnium Hf T =115 b) (Speer, 1982), an element that coexists with Zr in nature. This makes Zr ideal ...
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ژورنال
عنوان ژورنال: Journal of the Mining and Metallurgical Institute of Japan
سال: 1968
ISSN: 0369-4194,2185-6729
DOI: 10.2473/shigentosozai1953.84.963_1034